Recent Progress on Hyperbranched Polymers Synthesized via Radical-Based Self-Condensing Vinyl Polymerization
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چکیده
منابع مشابه
Recent Progress on Hyperbranched Polymers Synthesized via Radical-Based Self-Condensing Vinyl Polymerization
This short review article summarizes recent reports on using controlled radical polymerization (CRP) of inimers (compounds containing initiating group and vinyl group in one molecule) or transmers (compounds containing chain transfer group and vinyl group in one molecule) for the synthesis of hyperbranched polymers. These inimers and transmers that carry numerous functional groups could be homo...
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Introduction Highly branched polymers play an increasingly important role in interface and surface sciences, since their distinctive chemical and physical properties can be used advantageously as functional surfaces and as interfacial materials. Hyperbranched polymers grafted onto surfaces have also become a field of growing interest. Depending upon the substrates, it can be divided into 3D, 2D...
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Self-condensing vinyl hyperbranched polymerization (SCVP) with A-B* type monomer is simulated applying Monte Carlo method using 3d bond fluctuation lattice model in three-dimensional space. The kinetics of SCVP with zero active energy of reaction is studied in detail. It is found that the maximal number–average and weight–average polymerization degrees and the maximal molecular weight distribut...
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Exfoliated poly (Chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [P(CMSt-co-St)-g-PAN/O-MMT] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. At first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...
متن کاملSynthesis of hypergrafted poly[4-(N,N-diphenylamino)methylstyrene] through tandem anionic-radical polymerization of radical-inimer
In this paper, we present a tandem anionic-radical approach for synthesizing hypergrafted polymers. We prepared 4-(N,N-diphenylamino)methylstyrene (DPAMS) as a new radical-based inimer. Linear PDPAMS was prepared through anionic polymerization. Hypergrafted PDPAMS was synthesized through the self-condensing vinyl polymerization of DPAMS with linear PDPAMS. The linear backbone of PDPAMS, which i...
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ژورنال
عنوان ژورنال: Polymers
سال: 2017
ISSN: 2073-4360
DOI: 10.3390/polym9060188